5/30/2023 0 Comments Breuer condensed mediumThis is prompted by the need for a new theory of the microscopic processes behind the operation of a variety of solid state electrochemical devices (involving, for example, the metal/solid electrolyte interface). 6-10 In recent years the interest in reactions in the solid phase has increased. 4,5 Theoretical views on chemical charge transfer (focused on the reactions in electrolyte solutions, both in the bulk and at electrode surfaces), rooted in similar or closely related concepts and formalism, began to appear in the 1950's, with tremendous impact on all later work in this broad area of chemistry. The theory was later extended to the crystal defect mobility. ![]() 1-3 These included both electron-hopping mobility in polar crystals and light absorption and radiationless processes in impurity centers. Historically, the development of the theory of charge transfer began for solids where multiphonon electron transitions between localized states were discovered.
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